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2.1 INTRODUCTION This chapter presents applications of combinatorial algorithms and graph theory to problems in chemistry. Most of the techniques used are quite general, applicable to other problems from various elds. The problem of cell growth is one of the classical problems in combinatorics. Cells are of the same shape and are in the same plane, without any overlap. If h copies of the same shape are connected (two cells are connected by sharing a common edge), then they form an h-mino, polyomino, animal, or polygonal system (various names given in the literature for the same notion). Three special cases of interest are triangular, square, and hexagonal systems, which are composed of equilateral triangles, squares, and regular hexagons, respectively. Square and hexagonal systems are of genuine interest in physics and chemistry, respectively. The central problem in this chapter is the study of hexagonal systems. Figure 2.1 shows a molecule and its corresponding hexagonal system. Enumeration and exhaustive generation of combinatorial objects are central topics in combinatorial algorithms. Enumeration refers to counting the number of distinct objects, while exhaustive generation consists of listing them. Therefore, exhaustive generation is typically more demanding than enumeration. However, in many cases, the only available methods for enumeration rely on exhaustive generation as a way of counting the objects. In the literature, sometimes enumeration or constructive enumeration are also used to refer to what we call here exhaustive generation. An important issue for enumeration and exhaustive generation is the notion of isomorphic or equivalent objects. Usually, we are interested in enumerating or generating only one copy of equivalent objects, that is, only one representative from each isomorphism class. Polygonal systems are considered different if they have code 128 barcode generator asp.net VB6 - Code128 A,B and C-VBForums
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